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electron nuclear double resonance
Electron nuclear double resonance (ENDOR) is a magnetic resonance technique for elucidating the molecular and electronic structure of paramagnetic species.〔Kevan, L and Kispert, L. D. ''Electron Spin Double Resonance Spectroscopy'' Interscience: New York, 1976.〕 The technique was first introduced to resolve interactions in electron paramagnetic resonance (EPR) spectra.〔/〕〔Kurreck, H.; Kirste, B.; Lubitz, W. ''Electron Nuclear Double Resonance Spectroscopy of Radicals in Solution'' VCH Publishers: New York, 1988.〕 It is currently practiced in a variety of modalities, mainly in the areas of biophysics and heterogeneous catalysis.
==CW experiment==
In the standard continuous wave (cwENDOR) experiment, a sample is placed in a magnetic field and irradiated sequentially with a microwave followed by radio frequency. The changes are then detected by monitoring variations in the polarization of the saturated electron paramagnetic resonance (EPR) transition.〔/〕
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